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1 article(s) from Singh, Wangkhem P

A new class of organogelators based on triphenylmethyl derivatives of primary alcohols: hydrophobic interactions alone can mediate gelation

Wangkhem P. Singh and
Rajkumar S. Singh

Beilstein J. Org. Chem. 2017, 13, 138–149, doi:10.3762/bjoc.13.17

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Graphical Abstract

Scheme 1: Chemical structures of triphenylmethyl-based organogelators.

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Figure 1: Organogels formed by TPM-G12 in (a) propan-1-ol; (b) DMSO at 0.5% w/v; (c) organogel from TPM-G5 in...

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Figure 2: Plot of T_gel (gel–sol transition temperature) versus gelators at different concentrations. TPM-G12 ...

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Figure 3: DSC thermograms of gels prepared from TPM-G12 in (a) Propan-1-ol and (b) DMSO.

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Figure 4: SEM images of the dried gels. TPM-G12 in propan-1-ol (a) and (b), in DMSO (c) and (d); TPM-G5 in DM...

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Figure 5: Stress sweep rheological experiment of TPM-G12 gel (1.5% w/v) in (a) propan-1-ol (b) DMSO.

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Figure 6: FTIR spectra of gelator TPM-G12 in (a) CHCl₃ and (b) xerogel in KBr.

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Figure 7: Powder X-ray diffraction patterns of xerogel of (a) TPM-G12 from propan-1-ol and (b) TPM-G5 from DM...

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Figure 8: Energy minimized conformational structure of (a) TPM-G12 and (b) TPM-G5 obtained using B3LYP/6-31G ...

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Figure 9: Possible molecular packing arrangement in the self-assembled gel state of (a) TPM-G12 and (b) TPM-G5...

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Figure 10: Time-dependent UV–vis absorption profile of (a) Direct Red 80 (b) Crystal Violet aqueous dye soluti...

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Published 23 Jan 2017

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